Sunday, April 29, 2012

From Brockman with love, Chemistry Royale, Quantum of Molecular Solace: Octopussy

July 14, 2010 by  
Filed under Archive

Gus and Vinny’s chem project, created by Gus and Luis

If you’ll excuse the ridculously overdramatic soundtrack :) Synthesis of CdSe nanocrystals by injection of cadmium and selenium precursors into a high boiling point coordinating solvent at 360 degrees C. ~3nm particles of CdSe are initially generated. The intense color results from the quantum confinement effect on the electron as a result of the nanocrystal size being less than the Bohr radius of the exciton. Thus, as the particles grow larger, they become redder in color. A size series was generated by allowing the crystals to grow at 280C over a period of ~2 minutes. The visible spectrum from 515nm (green) to 650nm (red) was covered.
Video Rating: 4 / 5

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Comments

28 Responses to “From Brockman with love, Chemistry Royale, Quantum of Molecular Solace: Octopussy”
  1. Gustapopolice says:

    the final version is better… oh well, still a masterpiece!

    [Reply]

  2. retownsend says:

    gradefail

    [Reply]

  3. theboss1112 says:

    lol

    [Reply]

  4. lorenzom21 says:

    Epic

    [Reply]

  5. aliensmilez says:

    what is said overdramatic music?

    [Reply]

  6. AMonteverdi says:

    what happens if u mix them all together…?

    [Reply]

  7. Arissef says:

    Looks like every video (whatever it’s about) has to use this music.

    [Reply]

  8. vladislaowilly says:

    hey i love this videos, were i want to prepare some quantum dots like yours, were can i find the procedure

    [Reply]

  9. zweisteinJ says:

    music fail

    [Reply]

  10. Spastb00n says:

    I guess you are refering to the microscopic holes in nitrile gloves, that are in fact large enough to let nano-particles pass through?

    If that is the case, I wouldn’t be so sure, that they “don’t protect”. There still needs to be some sort of cause as to why they should enter these holes and your body.

    Unless it is a known problem, in which case I happily stand corrected.

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  11. partition00 says:

    sure it is

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  12. hinginator says:

    Absolutely agree. Cd is exceptionally toxic and the nanometric scale indicates they will easily permeate cellular membranes

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  13. germans1 says:

    Watch out for a company on the London aim market going places with this technology. ticker symbol nano.

    [Reply]

  14. apparent123 says:

    is that edible?

    [Reply]

  15. AliciaNoir says:

    i see what you mean by overly dramatic soundtrack haha, although it does build with the experiment. i loved watching the quantum dots at sussex uni, i was amazed by them. nice video.

    [Reply]

  16. kingoliver2111 says:

    wow good video

    [Reply]

  17. ytmachx says:

    Excellent video and super work! I wish I could have been there when you did it!

    [Reply]

  18. Okibum04 says:

    They can be used in vivo after ligand exchange, maybe CdSe won’t be used but InP could be.

    [Reply]

  19. goodnec says:

    requiem for a synthesis

    [Reply]

  20. guachipiruli says:

    the purple nitrile gloves are very fancy and fashionable but they don’t protect against possible spills of QD in the sizes you are synthesizing: not smart. They will never be used in vivo in humans.

    [Reply]

  21. aliyaapple says:

    not TOPO or TOP, is paraffin

    [Reply]

  22. rimpick says:

    Song-Requiem for a dream!
    sound even better with 2pac on it,-mix-.

    [Reply]

  23. hydrogen1219 says:

    I think they used a coordinating solvent that consists of TOP and TOPO. This solvent is very important to synthesize nanopartices because it can stablize the result colloidal dispersion as well as electronically passivate the semiconductor surface.

    [Reply]

  24. lexichronicle says:

    nice!

    [Reply]

  25. darkcurrent says:

    wow, you guys aren’t scared of getting cataract by turning that UV lamp upside down?

    [Reply]

  26. apparent123 says:

    The overdramatic music was good.

    [Reply]

  27. muschitrichter says:

    TOPO

    [Reply]

  28. muschitrichter says:

    I think TOPO

    [Reply]

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